Peeks group
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Spectroscopy
Global aromaticity at the nanoscale
Does aromaticity have a size limit? Evidence is presented for global aromaticity in porphyrin nanorings with circuits of up to 162 …
Michel Rickhaus
,
Michael Jirasek
,
Lara Tejerina
,
Henrik Gotfredsen
,
Martin Peeks
,
Renée Haver
,
Hua-Wei Jiang
,
Timothy D. W. Claridge
,
Harry L. Anderson
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Project
DOI
Mechanisms of IR amplification in radical cation polarons
Break down of the Born–Oppenheimer approximation is caused by mixing of electronic and vibrational transitions in the radical cations …
William J. Kendrick
,
Michael Jirásek
,
Martin Peeks
,
Gregory M. Greetham
,
Igor v. Sazanovich
,
Paul M. Donaldson
,
Michael Towrie
,
Anthony W. Parker
,
Harry L. Anderson
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DOI
Time-Resolved Structural Dynamics of Extended π-Electron Porphyrin Nanoring
The design of molecular structures inspired by naturally occuring light harvesting systems has been intensely pursued over the last …
Giovanni Bressan
,
Martin Peeks
,
Harry L. Anderson
,
Stephen R. Meech
,
Ismael A. Heisler
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DOI
Aromaticity and Antiaromaticity in the Excited States of Porphyrin Nanorings
Aromaticity can be a useful concept for predicting the behavior of excited states. Here we show that π-conjugated porphyrin nanorings …
Martin Peeks
,
Juliane Q. Gong
,
Kirstie McLoughlin
,
Takayuki Kobatake
,
Renée Haver
,
Laura M. Herz
,
Harry L. Anderson
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DOI
Global Aromaticity and Antiaromaticity in Porphyrin Nanoring Anions
Doping, through oxidation or reduction, is often used to modify the properties of π-conjugated oligomers. In most cases, the resulting …
Martin Peeks
,
Michael Jirasek
,
Timothy D. W. Claridge
,
Harry L. Anderson
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DOI
Detection of a weak ring current in a nonaromatic porphyrin nanoring using magnetic circular dichroism
We compare the absorption and magnetic circular dichroism (MCD) spectra of a series of porphyrin oligomers – dimer, tetramer, and …
Patrycja Kowalska
,
Martin Peeks
,
Tomasz Roliński
,
Harry L. Anderson
,
Jacek Waluk
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DOI
Electronic Delocalization in the Radical Cations of Porphyrin Oligomer Molecular Wires
The radical cations of a family of π-conjugated porphyrin arrays have been investigated: linear chains of N = 1–6 porphyrins, a …
Martin Peeks
,
Claudia E. Tait
,
Patrik Neuhaus
,
Georg M. Fischer
,
Markus Hoffmann
,
Renée Haver
,
Arjen Cnossen
,
Jeffrey R. Harmer
,
Christiane R. Timmel
,
Harry L. Anderson
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DOI
Aromatic and antiaromatic ring currents in a molecular nanoring
Aromatic and antiaromatic molecules—which have delocalized circuits of [4n + 2] or [4n] electrons, respectively—exhibit ring currents …
Martin Peeks
,
Timothy D. W. Claridge
,
Harry L. Anderson
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DOI
Harnessing NMR relaxation interference effects to characterise supramolecular assemblies
Solution-state NMR spectroscopy remains the primary method for characterising synthetic supramolecular assemblies. Yet, in their NMR …
Gogulan Karunanithy
,
Arjen Cnossen
,
Henrik Müller
,
Martin Peeks
,
Nicholas H. Rees
,
Timothy D. W. Claridge
,
Harry L. Anderson
,
Andrew J. Baldwin
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DOI
Experimental and computational evaluation of the barrier to torsional rotation in a butadiyne-linked porphyrin dimer
The barrier to torsional rotation in a butadiyne-linked porphyrin dimer has been determined in solution using variable temperature …
Martin Peeks
,
Patrik Neuhaus
,
Harry L. Anderson
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DOI
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