Photoexcited and ground-state diradical(oid) character in a triquino[3]radialene
Abstract
The unusual [3]radialene motif at the centre of triquino[3]radialene permits exceptional electronic conjugation between the three quinone arms of the molecule, giving rise to a remarkably low-energy and intense absorption spectrum. Since triquino[3]radialene’s initial synthesis in the 1970s, questions have been posed around the molecule’s potential diradical(oid) character. In this work we present new synthetic approaches to triquino[3]radialene and a thorough spectroscopic and computational evaluation of its properties. Despite broad UV-visible absorption, the triquino[3]radialene is non-emissive. An investigation by transient absorption spectroscopy reveals that the initially-formed excited state of triquino[3]radialene decays to a triplet state with a lifetime of 0.82 µs. Using computational chemistry, we compare triquino[3]radialene to Yang’s biradical and galvionxyl, with which it is structurally similar. DFT reveals insights into the role of aromaticity in the photoexcited triplet state, where quinoidal rings become more aromatic. MCSCF and CIPT2 calculations reproduce the experimental spectra and reveal a diradical character of y=0.05 in triquino[3]radialene.
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Bethany Hillier
PhD Student (2021-); Honours Student (2020-2021); Undergraduate researcher (2019)
Bethany completed a Bachelor of Science (International) at UNSW, supplementing her Chemistry major with a minor in Spanish and Latin American Studies. She has returned to the Peeks Group for her Honours Project in 2020, having previously researched as an undergraduate volunteer in 2019. Bethany is currently interested in the synthesis and properties of cross-conjugated molecules.
Stephen Bortolussi
PhD student (2021-); Honours Student (2020)
Stephen is from Sydney, Australia, and originally joined the Peeks group as an honours student in 2020, looking into the properties of liquid crystalline materials. He returned to the group in 2021 to start his PhD in Chemistry at UNSW. The current direction of his research is computational and synthetic studies into the electronic properties of (anti)aromatic molecules. He is also a teaching fellow with the UNSW School of Chemistry, and has an active role in the Students of Chemistry Society (SOCS).