Porphyrins

Linear π-conjugated porphyrin oligomers are of significant current interest due to their potential applications as molecular wires. In …

Quantum interference in charge transport is attracting interest with applications in nanoelectronics and quantum computing. Here, the …

Aromatic and antiaromatic molecules—which have delocalized circuits of [4n + 2] or [4n] electrons, respectively—exhibit ring currents …

Introducing bridging ligands such as DABCO to solutions of linear zinc porphyrin oligomers has previously been shown to lead to the …

Solution-state NMR spectroscopy remains the primary method for characterising synthetic supramolecular assemblies. Yet, in their NMR …

The barrier to torsional rotation in a butadiyne-linked porphyrin dimer has been determined in solution using variable temperature …

Excitation wavelength-dependent EPR and ENDOR reveal localization of the triplet state in twisted conformations of porphyrin oligomers.

The smallest and most strained member of a family of π-conjugated cyclic porphyrin oligomers was synthesized by using pentapyridyl …

The photoexcited triplet states of a series of linear and cyclic butadiyne-linked porphyrin oligomers were investigated by transient …