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Global aromaticity at the nanoscale
Does aromaticity have a size limit? Evidence is presented for global aromaticity in porphyrin nanorings with circuits of up to 162 …
March 2020 Nature Chemistry
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Global aromaticity at the nanoscale
Global Aromaticity and Antiaromaticity in Porphyrin Nanoring Anions
Doping, through oxidation or reduction, is often used to modify the properties of π-conjugated oligomers. In most cases, the resulting …
January 2019 Angewandte Chemie International Edition
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Global Aromaticity and Antiaromaticity in Porphyrin Nanoring Anions
Aromatic and antiaromatic ring currents in a molecular nanoring
Aromatic and antiaromatic molecules—which have delocalized circuits of [4n + 2] or [4n] electrons, respectively—exhibit ring currents …
January 2017 Nature
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Aromatic and antiaromatic ring currents in a molecular nanoring
Harnessing NMR relaxation interference effects to characterise supramolecular assemblies
Solution-state NMR spectroscopy remains the primary method for characterising synthetic supramolecular assemblies. Yet, in their NMR …
June 2016 Chem. Commun.
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Harnessing NMR relaxation interference effects to characterise supramolecular assemblies