NMR

Global aromaticity at the nanoscale
Nature Chemistry 2020
Does aromaticity have a size limit? Evidence is presented for global aromaticity in porphyrin nanorings with circuits of up to 162 …
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Global aromaticity at the nanoscale
Global Aromaticity and Antiaromaticity in Porphyrin Nanoring Anions
Angewandte Chemie International Edition 2019
Doping, through oxidation or reduction, is often used to modify the properties of π-conjugated oligomers. In most cases, the resulting …
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Global Aromaticity and Antiaromaticity in Porphyrin Nanoring Anions
Aromatic and antiaromatic ring currents in a molecular nanoring
Nature 2017
Aromatic and antiaromatic molecules—which have delocalized circuits of [4n + 2] or [4n] electrons, respectively—exhibit ring currents …
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Aromatic and antiaromatic ring currents in a molecular nanoring
Harnessing NMR relaxation interference effects to characterise supramolecular assemblies
Chem. Commun. 2016
Solution-state NMR spectroscopy remains the primary method for characterising synthetic supramolecular assemblies. Yet, in their NMR …
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Harnessing NMR relaxation interference effects to characterise supramolecular assemblies