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Global aromaticity at the nanoscale
Does aromaticity have a size limit? Evidence is presented for global aromaticity in porphyrin nanorings with circuits of up to 162 …
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Global aromaticity at the nanoscale
Mechanisms of IR amplification in radical cation polarons
Break down of the Born–Oppenheimer approximation is caused by mixing of electronic and vibrational transitions in the radical cations …
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Mechanisms of IR amplification in radical cation polarons
Time-Resolved Structural Dynamics of Extended π-Electron Porphyrin Nanoring
The design of molecular structures inspired by naturally occuring light harvesting systems has been intensely pursued over the last …
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Time-Resolved Structural Dynamics of Extended π-Electron Porphyrin Nanoring
Probing the orientation of porphyrin oligomers in a liquid crystal solvent – a triplet state electron paramagnetic resonance study
Linear porphyrin oligomers have found various applications as synthetic molecular wires in the context of light harvesting, solar …
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Probing the orientation of porphyrin oligomers in a liquid crystal solvent – a triplet state electron paramagnetic resonance study
Aromaticity and Antiaromaticity in the Excited States of Porphyrin Nanorings
Aromaticity can be a useful concept for predicting the behavior of excited states. Here we show that π-conjugated porphyrin nanorings …
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Aromaticity and Antiaromaticity in the Excited States of Porphyrin Nanorings
Global Aromaticity and Antiaromaticity in Porphyrin Nanoring Anions
Doping, through oxidation or reduction, is often used to modify the properties of π-conjugated oligomers. In most cases, the resulting …
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Global Aromaticity and Antiaromaticity in Porphyrin Nanoring Anions
Janus Graphene: Scalable Self-Assembly and Solution-Phase Orthogonal Functionalization
Orthogonal functionalization of 2D materials by selective assembly at interfaces provides opportunities to create new materials with …
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Janus Graphene: Scalable Self-Assembly and Solution-Phase Orthogonal Functionalization
Watching Bonds Move in a Large Antiaromatic Ring
In antiaromatic molecules, single and double bonds interconvert via a process called bond-shift valence tautomerization, which is often …
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Watching Bonds Move in a Large Antiaromatic Ring
Band Structures of Periodic Porphyrin Nanostructures
Recent progress in the synthesis of π-conjugated porphyrin arrays of different shapes and dimensionalities motivates us to examine the …
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Band Structures of Periodic Porphyrin Nanostructures
A Semiconducting Conjugated Radical Polymer: Ambipolar Redox Activity and Faraday Effect
Investigations of magnetism in electronically coupled polyradicals have largely focused on applications in photonic and magnetic …
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A Semiconducting Conjugated Radical Polymer: Ambipolar Redox Activity and Faraday Effect